Synthesis of 1,5-Pentanediol by Hydrogenolysis of Furfuryl Alcohol over Ni–Y2O3 Composite Catalyst

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Husni Wahyu Wijaya, Takashi Kojima, Takayoshi Hara, Nobuyuki Ichikuni, Shogo Shimazu

2017 ChemCatChem Vol. 9 Issue 14 Article Cited by 59

Abstract

The addition of Y2O3 into Ni formed a composite catalyst that selectively produced 1,5-pentanediol rather than 1,2-pentanediol in the hydrogenolysis of furfuryl alcohol at 2.0 MPa H2 and 423 K. Clearly, 1,5-pentanediol was produced over the Ni0–Y2O3 boundary. This report highlights the properties of Ni–Y2O3, catalytic performance, and reaction route in the synthesis of 1,5-pentanediol from furfuryl alcohol. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Affiliations

Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33, Yayoi, Inage, Chiba, 263-8522, Japan; Department of Chemistry, Faculty Mathematics and Science, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, 65145, East Java, Indonesia