A review on synthesis of kaolin-based zeolite and the effect of impurities

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Hartati, Didik Prasetyoko, Mardi Santoso, Imroatul Qoniah, Wai L. Leaw, Putri B. D. Firda, Hadi Nur

2020 Journal of the Chinese Chemical Society Vol. 67 Issue 6 Review Cited by 63 Quartile

Abstract

Zeolite is extensively synthesized for the application in a large variety of catalysis processes such as ion exchange, hydrocarbon cracking, and organic synthesis. In order to satisfy the serious terms of sustainability that denotes to the reduction of costs and chemical waste, kaolinite-based zeolites were produced from cheap natural resources as against to the conventional process that employs pure sodium silicate and sodium aluminate. This review paper is to highlight the current trends in the synthesis of zeolite. Prior to previous reviews, great concern is focused on the impurities effect on the catalytic performance of kaolinite-based zeolites. This study reveals that the impact of impurities in a catalytic reaction was in fact, underestimated or neglected. For instance, it was found that Fe ion concentration as small as 60 ppm gives significant catalytic output. Hence, a new practice to report the concentration of impurities in the research publication is suggested. This undoubtedly will generate a better interpretation of the catalytic activity from the zeolite framework. © 2020 The Chemical Society Located in Taipei & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Affiliations

Department of Chemistry, Faculty of Science and Technology, Universitas Airlangga, Kampus C UNAIR, Surabaya, Indonesia; Department of Chemistry, Faculty of Science Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia; Center for Sustainable Nanomaterials, Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, Johor Bahru, Malaysia; Central Laboratory of Minerals and Advanced Materials, Faculty of Mathematics and Natural Sciences, State University of Malang, Malang, Indonesia