Kevin Daffa Prasetya, Fahir Hassan, Yu-Ting Yen, Po-Yu Chen, Jheng-Jie Jiang, Ya-Fen Wang, Sheng-Jie You
Microplastics (MPs) are a new contaminant of global concern that have been found in wastewater treatment plants (WWTPs) as a result of human activities, which serve a dual function as critical barriers and pathways to natural waters and sludge-based applications. This study comprehensively evaluates the fate of MPs in multi-stage treatment units, covering both the water and sludge phases. It applies diversity assessments (Simpson Diversity Index [SDI], Shannon-Wiener Diversity Index [SWDI], and Principal Component Analysis [PCA]) and settling dynamics models (Mass Balance Model [MBM] and Terminal Settling Velocity Model [TSVM]). It was found that the concentration of MPs in water and sludge phases ranged from 2 to 1152 items/L and 35.65–85.05 × 103 items/kg DW, respectively. MPs removal at the Taoyuan WWTP achieved 97.42 % after nitrite-denitrification and phosphorus removal (TNCU) processes. Despite these high removal rates, fibers and fragments dominate the MPs in the water phases (35.36 % and 14.25 %) and sludge phases (21.06 % and 17.26 %), which are mostly 50–125 μm in size. Further confirmation of the polymer characteristics in both matrices revealed that rayon (51.12 %) and polystyrene (36.59 %) were dominant, respectively. Subsequently, the diversity assessments showed greater variation and homogeneity of MPs characteristics in the sludge phases than in the water phases. Meanwhile, PCA results showed that specific MP characteristics (e.g., shape, size, polymer type) significantly influenced their grouping patterns across treatment stages. Among settling dynamics fate models implemented in this study, MBM confirmed that MPs are accumulated in the sludge phases, while TSVM indicated that the settling mechanisms of MPs was strongly influenced by their size and density. These findings offer new insights into MPs' fate and behavior in WWTPs, supporting the development of more effective mitigation strategies. © 2025 Elsevier B.V.
Department of Civil Engineering, Chung Yuan Christian University, Zhongli, Taoyuan, 32023, Taiwan; Department of Environmental Engineering, Chung Yuan Christian University, Zhongli, Taoyuan, 32023, Taiwan; Center for Environmental Risk Management, Chung Yuan Christian University, Zhongli, Taoyuan, 32023, Taiwan; Environmental Engineering Study Program, Department of Civil Engineering, State University of Malang, Malang, 65145, Indonesia; Sustainable Environmental Education Center, Chung Yuan Christian University, Zhongli, Taoyuan, 32023, Taiwan
