I. Wayan Dasna, Ubed Sonai Fahruddin Arrozi, Husni Wahyu Wijaya, Sutandyo Dwija Laksmana, Stéphane Golhen
Two complexes of [Mn(Quin)2(N(CN)2)2]∞ (1) and [Co(Quin)2(N(CN)2)2]∞ (2) were synthesized and characterized. The as-synthesized complexes crystallized in a triclinic lattice with a space group of P-1. The unit cell parameter of 1 was a = 7.5207(14) Å, b = 7.7729(16) Å, c = 9.5968(15) Å, α = 96.388(6)o, β = 112.617(5)o, γ = 102.751(6)o, while for complex 2 it was a = 7.3942(10) Å, b = 7.7960(10) Å, c = 9.4907(13) Å, α = 96.631(4)o, β = 112.742(4)o, γ = 102.458(4)o. The magnetic properties and antimicrobial properties of both polymeric complexes were examined by magnetic susceptibility and diffusion techniques, respectively. Complexes 1 and 2 both showed antiferromagnetic properties and had a higher inhibitory effect on the growth of Staphylococcus aureus than Salmonella typhi. © 2022 Published by ITB Institut for Research and Community Service,.
Department of Chemistry, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Jawa Timur, Malang, 65145, Indonesia; Centre of Advanced Material for Renewable Energy, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Jawa Timur, Malang, 65145, Indonesia; University of Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes), UMR 6226, Rennes, 35000, France