Nadiya Ayu Astarini, Akhmad Al Ittikhad, Markus Diantoro, Nasikhudin, Rahmat Hidayat, Herlin Pujiarti
The design innovation and composition of TiO2 as a photoanode have been continuously studied in recent years to improve the photoconversion performance of Dye-sensitized Solar Cells (DSSC). The important components in the formation of TiO2 paste are solid content, solvents, and organic compounds as binders. In terms of solvents, water or simple alcohol are not suitable for screen printing methods, because cracking will occur after the annealing process by rapid evaporation. In this report, we investigated the addition of nitric acid (HNO3) and ethyl cellulose (CH2CH3) as a binder for optimize the overall DSSC performance. TiO2 photoanode was synthesized by screen printing method through the initial stage of making blocking layer with spin coating method. The effect of nitric acid and ethyl cellulose on TiO2 powder was studied intensively to determine the best photoconversion performance. TiO2 films were prepared by varying the process without and with post-treatment. The XRD pattern confirmed the presence of a pure anatase phase of TiO2. The morphology of the photoanodes surface area were studied through SEM characterization. The characteristics of J-V shows an increasing in photocurrent and efficiency through the post-treatment process. DSSCs based on TiO2-HNO3 photoanode with post-treatment exhibited a highest efficiency of 3.59%. We found that the sample with post-treatment process have a smaller impedance than sample without post-treatment with charge transfer resistance (RCT) of 10 Ω and 23 Ω, respectively. It may indicate that the TiO2 film with post-treatment have a better interconnection then charge transfer and charge extraction process are more effective and resulting higher efficiency. © 2023 American Institute of Physics Inc.. All rights reserved.
Departement of Physics, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, Jl. Semarang No. 5, Malang, 651145, Indonesia; Center of Advanced Materials for Renewable Energy (CAMRY), Universitas Negeri Malang, Jl. Semarang, No. 5, Malang, 651145, Indonesia; Physics of Magnetism and Photonics Research Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung, 40132, Indonesia