Ionic liquid (1-ethyl-3-methyltricynomethanide) doped polymer electrolyte (polyvinyl alcohol) for sustainable energy devices

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Abhimanyu Singh, Pawan Singh Dhapola, Subhrajit Konwar, Tejas Sharma, H.K. Jun, Diksha Singh, Karol Strzałkowski, M.N. Masri, M.Z.A. Yahya, Markus Diantoro, Pramod K. Singh

2023 Journal of Science: Advanced Materials and Devices Vol. 8 Issue 3 Article Cited by 11 Quartile

Abstract

Polyvinyl alcohol (PVA) polymer mixed with different weight ratios of 1-ethyl-3-methyltricynomethanide (EMIm-TCM) ranging from 0 to 30 wt% were used to develop solid polymer electrolytes (SPEs). The structural, electrical, and electrochemical properties of the SPEs films were extensively studied. Introducing ionic liquid (IL) into PVA's structure improved its mechanical properties, flexibility, and conductivity, increasing application potential in energy devices. The maximal ionic conductivity of 3.85 × 10−4 Scm−1 was achieved by adding 30 wt% IL. Structural and morphology analysis was performed. Obtained materials exhibited enhanced amorphous nature, and the FT-IR spectrum showed perfect complexation, supported by our XRD pattern. The ionic transference number measurement (tion) confirms that ionic liquid doped polymer electrolyte (ILDPE) is predominantly ionic. Several devices were tested. ILDPE film sandwiched Electric double-layer capacitor (EDLC) and Dye-Sensitized Solar Cell (DSSC) showed a favorable response. © 2023 Vietnam National University, Hanoi

Affiliations

Center for Solar Cells & Renewable Energy, Department of Physics, Sharda University, Greater Noida, 201310, India; Lee Kong Chian Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Sungai Long Campus, Bandar Sg. Long, Kajang, 43000, Malaysia; Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University, Grudziadzka 5, Torun, 87-100, Poland; Universiti Malaysia Kelantan, Faculty of Bioengineering and Technology, Jelikelantan, 17600, Malaysia; Faculty of Defence Science and Technology, Universiti Pertahanan Nasional Malaysia (UPNM), Kuala Lumpur, 57000, Malaysia; Department of Physics, Faculty of Mathematics and Natural Science, Universitas Negeri Malang, J1, Semarang 5, Malang, 65145, Indonesia; Department of Molecular Physics, Faculty of Chemistry, Łodz University of Technology, Zeromskiego 116, 90-924 Łodz, Poland