Facile Synthesis of Activated Carbon-Polyaniline Composites as Electrode Material for Application in Supercapacitor

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Viona Lidya Haryati Putri, Nandang Mufti, Jeniva Dinta Nanda Fahreza, Salsabilla Nazla Husna, Silvi Rahmawati Wibowo

2024 Solid State Phenomena Vol. 363 Book chapter Cited by 0 Quartile

Abstract

Developing energy storage systems has become a significant focus in supporting advancing renewable energy technologies and electric vehicles. Super capacitors are a critical device in thisend eavor, known for their high capacitance and low internal resistance. Although carbon-based super capacitors have been widely used, they have low energy density. This research addresses the development of activated carbon (AC) and polyaniline (PANi) composite-based super capacitors to improve the performance of energy storage devices. AC/PANi composites were synthesized in various ratios of (20:80)%, (50:50)%, and (80:20)% using in-situ polymerization method. Super capacitor electrodes were prepared by mixing AC/PANi composite, acetylene black, and polyvinylidene fluoride (PVDF) with a mass ratio of (80:10:10)%. Furthermore, coin-type super capacitor cells were assembled using AC/PANi composite electrodes, 1 M Et4NBF4 electrolyte, and polypropylene separator. Super capacitor performance was evaluated using Cyclic Voltammetry(CV) methods. The results of FTIR analysis showed that the AC/PANi composite was successfully synthesized, with absorption peaks corresponding to the characteristics of AC and PANi. X-ray diffraction patterns showed that the AC/PANi composite exhibited amorphous properties. The CVtest results show that the coin cell based on the AC/PANi composite (20%:80%) indicates the highest performance with significant specific capacitance. Thus, super capacitor electrodes based on the AC/PANi composite show potential as active materials for super capacitor devices. © 2024 Trans Tech Publications Ltd, All Rights Reserved.

Affiliations

Department of Physics, Faculty of Mathematics and Natural Science, State University of Malang, Jl. Semarang 5, Malang, 65145, Indonesia; Centre of Advanced Materials for Renewable Energy, State University of Malang, Jl. Semarang 5, Malang, 65145, Indonesia