Ionic liquid (1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate) doped polyethylene polymer electrolyte for energy devices

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Suneyana Rawat, Pramod K. Singh, Amrita Jain, Shufeng Song, M.Z.A. Yahya, Serguei V. Savilov, Markus Diantoro, Monika Michalska, Anji Reddy Polu, Ram Chandra Singh

2024 Journal of Materials Science: Materials in Electronics Vol. 35 Issue 24 Article Cited by 15 Quartile

Abstract

This paper provides a comprehensive overview of the influence of 1-Butyl-1-Methylpyrrolidinium Trifluoromethanesulfonate (BMPyrrOTf)-ionic liquid on a new polymer electrolyte where Polyethylene oxide (PEO) as host and ammonium iodide (NH4I) as salt. These IL-doped solid polymer electrolyte were prepared using solution cast technique. Various characterisation techniques have been utilized to evaluate the qualitative and quantitative estimation of polymer electrolyte like Polarized microscopy (POM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Linear sweep voltammetry (LSV), Ionic transference no. (tion) and Impedance spectroscopy. Doping IL increases conductivity and highest achieve at 8 wt% of BMPyrrOTF with conductivity value reaches upto 4.15 × 10–5 S/cm at. Using Wagner’s polarization method, Ionic transference measurement support ionic conduction while stable potential window has further affirmed good electrochemical stability of films. The highest conducting IL-enriched polymer electrolyte sandwiched low-cost dye-sensitized solar cells (DSSCs) and electric double layer capacitors (EDLCs) have been developed, and their performance is conveniently appropriate. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024.

Affiliations

Center for Solar Cells and Renewable Energy (CSRE), Department of Physics, SSBSR, Sharda University, Greater Noida, 201310, India; Institute of Fundamental Technological Research, Polish Academy of Sciences, Pawińskiego 5B, Warsaw, 02-106, Poland; College of Aerospace Engineering, Chongqing University, Chongqing, 400044, China; Faculty of Defence Science and Technology, Universiti Pertahanan Nasional Malaysis (UPNM), Kuala Lumpur, 57000, Malaysia; Department of Chemistry, Lomonosov Moscow State University, 1-3 Lenniskiye Gory, Moscow, 119991, Russian Federation; Department of Physics, Faculty of Mathematics and Natural Science, Universitas Negeri Malang, Malang, 65145, Indonesia; Department of Chemistry and Physico-Chemical Processes, Faculty of Materials Science and Technology, VSB-Technical ˇ University of Ostrava, 17. listopadu 2172/15, Poruba, Ostrava, 708 00, Czech Republic; Department of Physics, BVRIT HYDERABAD College of Engineering for Women, Telangana, Hyderabad, 500090, India