Layered nickel cobalt hydrogen phosphate for high performance of supercapattery electrode

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Wulan Kusuma Wardani, Ni Luh Wulan Septiani, Siti Wihdatul Himmah, Ida Hamidah, Markus Diantoro, Andrivo Rusydi, Huda Abdullah, Brian Yuliarto

2024 Journal of Materials Science: Materials in Electronics Vol. 35 Issue 16 Article Cited by 2 Quartile

Abstract

This work reports on the preparation of nickel cobalt hydrogen phosphate as an electrode for supercapatteries. The morphology of the hydrogen phosphate was controlled by varying the ethanol-to-water ratio to 1:0, 5:1, 3:1, 2:1, and 1:1. It was found that a higher proportion of water resulted in a layered structure of the products. X-ray diffraction patterns and infrared spectra confirmed the formation of nickel cobalt hydrogen phosphate. As supercapattery electrode, the sample prepared with an ethanol-to-water ratio of 2:1, denoted as NiCoP1-4 exhibited a high specific capacity of 424 Cg−1 at a current density of 0.5 Ag−1 surpassing that of the electrode prepared using only ethanol. Furthermore, NiCoPi-4 demonstrated high stability with 96.3% retention after 5000 cycles. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024.

Affiliations

Advanced Functional Materials Laboratory, Faculty of Industrial Technology, Institut Teknologi Bandung, Bandung, 40132, Indonesia; Research Center for Nanotechnology System, National Research and Innovation Agency (BRIN), South Tangerang, 15314, Indonesia; Universitas Pendidikan Indonesia, Jl. Dr. Setiabudhi No. 229, Bandung, 40154, Indonesia; Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, Jl. Semarang 5, Malang, 65145, Indonesia; Center of Advanced Material for Renewable Energy (CAMRY), Universitas Negeri Malang, Jl. Semarang 5, Malang, Indonesia; Faculty of Science, National University of Singapore, 21 Lower Kent Ridge Rd, Singapore, 119077, Singapore; Department of Electrical, Electronic and System Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, Selangor, Bangi, 43600, Malaysia; Research Center for Nanosciences and Nanotechnology (RCNN), Institut Teknologi Bandung, Bandung, 40132, Indonesia