Sumari Sumari, Sukrawati Arni, Aman Santoso, Liqanatul Putri Sholikah, Muhammad Roy Asrori, Agus Budianto
Malang quartzite contains a highly silica content. The silica changes the structural composition of Zeolite Y. Currently, a heterogeneous catalyst is developed to optimize transesterification of Off Grade CPO (Crude Palm Oil). The aims of this study are: (1) synthesize K2O/Zeolite Y using silica from Malang quartzite, (2) synthesize methyl esters from Off Grade CPO using K2O/Zeolite Y catalyst, and (3) to evaluate quartzite based-silica contribution in Zeolite Y for the reaction activity via GC-MS analysis. The experimental stages were: the oil preparation, esterification of the prepared oil, preparation of K2O/zeolite Y catalyst, and the transesterification. This study applied variations of [KOH] in Zeolite Y (10, 20, and 30 % w/w) and the concentration of the transesterification catalyst (2, 3, and 4 % w/w). The K2O/Zeolite Y catalyst was successfully synthesized by impregnation method. Methyl esters of Off Grade CPO resulted the highest yield of 95.05 % with 4 wt% of 30-K2O/Zeolite Y (30 % KOH impregnation). The synthesized methyl esters have a density of 0.877 g/mL, a viscosity of 4.6 cSt, a refractive index of 1.445 and an acid number of 0.384 mg/g according to the standard (SNI 7182:2015). The main components of the methyl ester based on GC-MS results were methyl octanoate, methyl decanoate, methyl dodecanoate, methyl 9-octadecanoate, methyl octadecanoate and methyl tetracosanoate. Using quartzite-based silica, a co-activity of the reaction has occurred. © 2024
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, Jl. Semarang No. 5, Malang, 65145, Indonesia; Chemical Engineering Department, Faculty of Technology, Surabaya Institute of Adhi Tama Technology, Jalan Arief Rachman Hakim Surabaya 60117, Indonesia
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