Enhancing mechanical and thermal properties of bio-composites: Synergistic integration of ZnO nanofillers and nanocrystalline cellulose into durian seed starch matrix

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Femiana Gapsari, Sis Nanda Kus Andrianto, Afifah Harmayanti, Abdul Mudjib Sulaiman, Christina Wahyu Kartikowati, Kartika A. Madurani, Widya Wijayanti, Sanjay Mavinkere Rangappa, Suchart Siengchin

2025 International Journal of Biological Macromolecules Vol. 290 Article Cited by 13 Quartile

Abstract

The increasing demand for sustainable materials necessitates advancements in bio-composites with enhanced properties. This study addresses the limitations of Durio zibethinus Murr (DZM) seed starch bio-composites, particularly their poor mechanical strength and thermal stability. Using solution casting, zinc oxide (ZnO) nanofillers and nanocrystalline cellulose (NCC) were incorporated into the starch matrix. The optimized composite with 0.4 g ZnO exhibited a significant improvement in crystallinity (79.40 %), tensile strength (0.44 MPa), and thermal stability (15.54 % residual mass). These findings highlight the potential of the developed bio-nanocomposites for applications in food packaging and medical devices, combining enhanced durability with environmental sustainability. © 2024 Elsevier B.V.

Affiliations

Department of Mechanical Engineering, Faculty of Engineering, Brawijaya University, MT Haryono 167, Malang, 65145, Indonesia; Department of Mechanical Engineering, Faculty of Engineering, State University of Malang, Semarang 5, Malang, 65145, Indonesia; Department of Chemical Engineering, Faculty of Engineering, Brawijaya University, MT Haryono 167, Malang, 65145, Indonesia; Department of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Arief Rahman Hakim, Surabaya, 60111, Indonesia; Natural Composites Research Group Lab, Department of Materials and Production Engineering, The Sirindhorn International Thai-German Graduate School of Engineering (TGGS), King Mongkut's University of Technology North Bangkok (KMUTNB), Bangkok, 10800, Thailand