Effect of Fe3O4 on the Electro-Optic and Magneto-Electric Characteristics of (PANI/Fe3O4)-Ag Film

Open

M. Diantoro, D. Pradhana, A.A. Mustikasari, A.D. Kusumawati, A. Taufiq, Sunaryono, N. Mufti, H. Nur

2017 IOP Conference Series: Materials Science and Engineering Vol. 202 Issue 1 Conference paper Cited by 14

Abstract

(PANI/Fe3O4)-Ag films have been successfully synthesized on a glass substrate. In this study, PANI functioned as a matrix, Ag as a catalyst enhancing the conductivity of PANI, and Fe3O4 as the influence of magnetic properties. (PANI/Fe3O4)-Ag was synthesized by a combination of chemical polymerization method to introduce Ag doping into PANI, and coprecipitation method of Fe3O4. The samples were characterized by using FTIR, X-RD, SEM, EDAX, 4-probe electrical conductivity under the employing of magnetic fields, and under the influence of light intensity. It was shown that there was a Fe2O3 phase as the consequence of Fe3O4 oxidized as AgNO3 protonation on the ultrasonication treatment. introducing Fe3O4 into (PANI/Fe3O4)-Ag film, increase the surface density, but reduce the electrical conductivity. The increasing of magnetic field might also reduce the conductivity of (PANI/Fe3O4)-Ag. Further, We also obtained that the increasing of light intensity employed to the samples enhances the electrical conductivity. The electrical conductivity of (PANI/Fe3O4)-Ag can be tuned by controlling the Fe3O4, magnetic field, as well as the light intensity. © Published under licence by IOP Publishing Ltd.

Affiliations

Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, State University of Malang, Jl. Semarang No 5, Malang, 65145, Indonesia; Central Laboratory of Minerals, Advanced Materials Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, State University of Malang, Jl. Semarang No 5, Malang, 65145, Indonesia; Centre for Sustainable Nanomaterials, Ibnu Sina Institute for Scientific, Industrial Research Universiti Teknologi Malaysia, UTM Skudai, Johor, 81310, Malaysia