Effendy, Fabio Marchetti, Alessandro Marinelli, Claudio Pettinari, Brian W. Skelton, Allan H. White
Syntheses, spectroscopic and thermal characterization are reported for the potentially tetradentate bis(O,O′-4-acyl-5-pyrazolone) pro-ligands HQ3QH and HQ4QH (in detail HQ3QH: 1,5-bis(5-hydroxy-1-phenyl-3-methyl-1H-pyrazol-4-yl) pentane-1,5-dione, HQ4QH: 1,6-bis(5-hydroxy-1-phenyl-3-methyl-1H-pyrazol-4-yl) hexane-1,6-dione) and their di-n-butyltin(IV) derivatives [(Q3Q)SnBu2n]2 and [(Q4Q)SnBu2n]2. Single crystal X-ray structural characterizations of the proligand HQ4QH and of the binuclear tin(IV) complex [(Q3Q)SnBu2n]2 are also reported; both the ligand and complex molecules are centrosymmetric, the latter having two independent molecules in the structure. Sn-C, O(acyl), O(pz) distances (〈 〉) are 2.121(3), 2.119(6) and 2.37(4) . © 2010 Elsevier B.V. All rights reserved.
Chemistry M313, School of Biomedical, Biomolecular and Chemical Sciences, University of Western Australia, Crawley, WA 6009, Austria; Jurusan Pendidikan Kimia, FMIPA Universitas Negeri Malang, Malang 65145, Jalan Surabaya 6, Indonesia; School of Science and Technology, Universit Degli Studi di Camerino, 62032 Camerino MC, via S Agostino 1, Italy; School of Pharmacy, Universit Degli Studi di Camerino, 62032 Camerino MC, via S Agostino 1, Italy
