Syntheses, spectroscopic and structural characterization of some (solvated) binuclear adducts of the form Ag(oxyanion):dpem(:S) (1:1(:x))2 (oxyanion = ClO4, F3CCO2, F3CSO 3; dpem = Ph2E(CH2)EPh2 (E = P, As))

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Effendy, Corrado Di Nicola, Maksum Nitiatmodjo, Claudio Pettinari, Brian W. Skelton, Allan H. White

2005 Inorganica Chimica Acta Vol. 358 Issue 3 Article Cited by 48

Abstract

Syntheses, spectroscopic (IR, NMR and ESI MS) and single crystal X-ray structural characterizations are reported for a wide variety of adducts of Ag(oxyanion):dpem(:S) (1:1(:n))2 (oxyanion = ClO4, F 3CCO2 (tfa) F3CSO3 (tfs); dpem = Ph2E(CH2)EPh2) stoichiometry among which the basic Ag(Ph2E(CH2)EPh2)2Ag core is diversely perturbed by interactions with anions and solvent molecules. ESI MS and 31P NMR spectroscopy indicated that dinuclear species also exist in solution. © 2004 Elsevier B.V. All rights reserved.

Affiliations

Jurusan Kimia, FMIPA Universitas Negeri Malang, Jalan Surabaya 6, Malang 65145, I., Indonesia; Chemistry M313, The University of Western Australia, Crawley, WA 6009, Australia, Australia; Dipartimento di Scienze Chimiche, Univ. degli Studi di Camerino, Via S. Agostino 1, 62032 Camerino M., Italy

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