Synthesis and structural characterization of some adducts of 1,4-dithian and -oxathian with silver(I) nitrate and perchlorate

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Effendy, Sidik Bin Silong, Brian W. Skelton, Allan H. White

2003 Australian Journal of Chemistry Vol. 56 Issue 1 Article Cited by 6

Abstract

The crystallographic structures of 1,4-oxathian (O(CH2CH2)2S) and its 1:1 silver(I) nitrate adduct were redetermined The 1:1 and 1.5:1 adducts of 1,4-dithian (S(CH2CH2)2S) with silver(I) nitrate and perchlorate, respectively, were also determined. The nitrate complexes formed two-dimensional polymers while the perchlorate formed a three-dimensional polymer (see Figure). The Ag coordination environments were unique in each complex formed.

Affiliations

Chemistry, University of Western Australia, Crawley, WA 6009, Australia; Jurusan Pendidikan Kimia, FMIPA Universitas Negeri Malang, Malang 65145, Jalan Surabaya 6, Indonesia; Jabatan Kimia, Universiti Pertanian Malaysia, 43400 Serdang, Selangor, Malaysia