Effendy, John V. Hanna, Claudio Pettinari, Riccardo Pettinari, Carlo Santini, Brian W. Skelton, Allan H. White
The synthesis and spectroscopic (IR, far-IR, 1H and 31P NMR) characterization of the new complex Ag(pzTp)(PPh3)2 is reported, with a single crystal X-ray structure determination showing it to assume the form [(Ph3P)2Ag(pz2Bpz2)]. Although the silver atom is essentially four-coordinate P2AgN2, Ag-P 2.4154(4) Å, 2.5123(4) Å, Ag-N 2.315(1) Å, 2.357(1) Å at ca. 150 K, NMR spectroscopy clearly distinguishes between the bonding character of the two different phosphorus atoms. © 2007 Elsevier B.V. All rights reserved.
Chemistry M313, School of Biomedical, Biomolecular and Chemical Sciences, The University of Western Australia, Crawley, WA 6009, Australia; Jurusan Pendidikan Kimia, FMIPA Universitas Negeri Malang, Malang, 65145, Jalan Surabaya 6, Indonesia; ANSTO NMR Facility, Institute of Materials and Engineering Science, Lucas Heights Research Laboratories, Lucas Heights, NSW 2234, Australia; Dipartimento di Scienze Chimiche, Universitá degli Studi di Camerino, 62032 Camerino, MC, via S. Agostino 1, Italy
