Chitosan-tripoly phosphate (CS-TPP) synthesis through cross-linking process: The effect of concentration towards membrane mechanical characteristic and urea permeation

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Retno Ariadi Lusiana, Wahyu Putri Protoningtyas, Anugrah Ricky Wijaya, Dwi Siswanta, Mudasir, Sri Juari Santosa

2017 Oriental Journal of Chemistry Vol. 33 Issue 6 Article Cited by 35

Abstract

Crosslinking reactions are required to modify the functional groups on chitosan and to increase the number of active groups of chitosan. In this study crosslinking reaction of tripolyphospate (TPP) groups on chitosan was conducted in order to produce membrane which functions as candidate of hemodialysis membrane. The mole ratio between chitosan and NaTPP was varied to obtain the best composition of modified materials. Study of TPP concentration effect towards membrane characteristics was conducte durea permeation ability.The resulting membrane was then characterized including tests of thickness, water uptake, tensile strength and membrane hydrophilicity. The results showed that the best composition of membrane occurred in the addition of 0.691 g of NaTPP proved byin creasing water uptake (150%), its highest mechanical strength and releasing the percentage of urea permeation by 44%. © 2017 Oriental Scientific Publishing Company. All Rights Reserved.

Affiliations

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Semarang, Indonesia; Chemistry Department, Faculty Mathematics and Natural Sciences, Universitas Negeri Malang (UM), State University of Malang, Indonesia; Chemistry Department, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Yogyakarta, Indonesia